But ______  pts. out of  80 pts.  = _________ % =                                     Name:

 

Advanced Chemistry:  Test #3 (Atomic Theory & Periodic Trends)

 

Multiple Choice:  On the answer sheet darken the letter corresponding to the best answer.  (1 pt. each)

 

1.     According to the Aufbau order, which of the following has a half-filled subshell? 

   

 a.  Ca 

 b.  Si  

 c.  S 

 d.  Sb 

 e.  Fe 

 

2.     Which of the following statements is true? 

  

 a.  The frequency of green light is higher than blue light, and the wavelength of green light is higher than blue light. 

 b. The frequency of green light is higher than blue light, and the wavelength of green light is lower than blue light. 

 c. The speed of green light is higher than blue light, and the frequency of green light is lower than blue light. 

 d. The frequency of green light is lower than blue light, and the wavelength of green light is lower than blue light. 

 e. The frequency of green light is lower than blue light, and the wavelength of green light is higher than blue light. 

  

 3.    As the wavelength of electromagnetic radiation increases: 

   

 a.  its energy increases  

 b.  its frequency increases  

 c.  its speed must increase  

 d.  more than one of the above are true   

 e.  none of the above is true 

    

4.     An orbital is a region around the nucleus: 

   

 a.  where an electron is always found   

 b.  that defines the exact path of an electron   

 c.  where there is a high probability of finding an electron  

 d.  that defines the average distance of an electron from the nucleus  

 e.  that can contain one or more subshells of electrons 

  

5.     In comparing the radii of an antimony (Sb) atom and a tellurium (Te) atom (atomic numbers 51 & 52): 

   

 a.  Te has a larger radius because it has more electrons.   

 b.  Sb has a larger radius because it has fewer protons, so the outer shell isn't pulled in as tightly. 

 c.  Sb has a smaller radius because it is has a half-filled p subshell.   

 d.  they both have about the same radius because they are both metalloids. 

 e.  they both have about the same radius because of  the shielding effect. 

 

 

 

 

6.     In comparing the first ionization energy (IE1) of calcium (Ca) and magnesium (Mg): 

   

 a.  Ca has a higher IE1 because its radius is smaller.   

 b.  Mg has a higher IE1 because its radius is smaller.   

 c.  Ca has a higher IE1 because its s subshell is full.   

 d.  Mg has a higher IE1 because its s subshell is full.   

 e.  they both have about the same IE1 because they have the same number of electrons in their outer shells.  

 

7.     In comparing the radii of a nitrogen (N) atom and phosphorus (P) atom: 

   

 a.  Phosphorus has a larger radius because it has more electrons.   

 b.  Nitrogen has a larger radius because it has fewer protons, so the outer shell isn't pulled in as tightly. 

 c.  Phosphorus has a larger radius because it needs an additional electron shell to accommodate its electrons. 

 d.  Nitrogen has a larger radius because it has a half-filled p subshell. 

 e.  they both have about the same radius because of  the shielding effect. 

 

 8.    In comparing the first ionization energy (IE1) of beryllium (Be) and boron (B): 

   

 a.  Be has a higher IE1 because its radius is smaller.  

 b.  B has a higher IE1 because its radius is smaller.   

 c.  Be has a higher IE1 because its s subshell is full.  

 d.  B has a higher IE1 because its s subshell is full.   

 e.  They both have about the same IE1 because B only has one more electron than Be. 

 

9.     In comparing the radii of a titanium (Ti) atom and a chromium (Cr) atom: 

   

 a.  Cr has a larger radius because it has more electrons.   

 b.  Ti has a larger radius because it has fewer protons, so the outer shell isn't pulled in as tightly. 

 c.  Cr has a larger radius because it needs an additional electron shell to accommodate its electrons. 

 d.  Ti has a larger radius because it has an extra energy level in its electron configuration. 

 e.  They both have about the same radius because of the shielding effect. 

 

10.   Sodium (Na) and potassium (K) are chemically very similar because: 

   

 a.  they have about the same atomic radius   

 b.  they have about the same ionization energy   

 c.  they have about the same electron affinity   

 d.  they have the same number of electrons in their outer shells   

 e.  they are both solids at room temperature    

 

11.   In comparing the electron affinity (EA) of phosphorus (P) and nitrogen (N):   

 

 a.  phosphorus has a higher EA because its radius is smaller.   

 b.  nitrogen has a higher EA because its radius is smaller.   

 c.  phosphorus has a higher EA because its p subshell is half full.   

 d.  nitrogen has a higher EA because its p subshell is half full.   

 e.  They both have about the same EA because they have the same number of electrons in their outer shells.  

 

 

 

 

 

  

12.   In comparing the radii of a chromium (Cr) atom and a Molybdenum (Mo) atom: 

   

 a.  Mo has a larger radius because it has more electrons.   

 b.  Cr has a larger radius because it has fewer protons, so the outer shell isn't pulled in as tightly. 

 c.  Mo has a larger radius because it needs an additional electron shell to accommodate its electrons. 

 d.  Cr has a larger radius because it has a half-filled d subshell. 

 e.  They both have about the same radius because of the shielding effect. 

  

13.   In comparing the electron affinity (EA) of sulphur (S) and phosphorus (P): 

 

 a.  S has a higher EA because its radius is smaller.   

 b.  P has a higher EA because its radius is smaller.   

 c.  S has a higher EA because its p subshell is half full.   

 d.  P has a higher EA because its p subshell is half full.  

 e.  They both have about the same EA because they are right next to each other in the periodic table. 

 

14.   In comparing the nonmetallic activity of sulphur (S) and selenium (Se): 

 

 a.  Sulphur is more active because it has a lower electron affinity.   

 b.  Selenium is more active because it has a lower electron affinity.   

 c.  Sulphur is more active because it has a higher electron affinity.  

 d.  Selenium is more active because it has a higher electron affinity.  

 e.  They both have about the same activity, because they both have the same number of valence electrons. 

  

 15.  In comparing the metallic activity of calcium (Ca) and strontium (Sr):   

 

 a.  Ca is more active because it has a higher ionization energy. 

 b.  Sr is more active because it has a higher ionization energy.  

 c.  Ca is more active because it has a lower ionization energy.  

 d.  Sr is more active because it has a lower ionization energy.   

 e.  They both have about the same activity, because they have the same number of valence electrons.  

 

16.   Nonmetals can be described as follows: 

   

 a.  brittle, good conductors of heat and electricity, gain electrons easily  

 b.  brittle, good conductors of heat and electricity, lose electrons easily   

 c.  brittle, poor conductors of heat and electricity, lose electrons easily   

 d.  brittle, good conductors of heat and electricity, gain electrons easily   

e.       brittle, poor conductors of heat and electricity, gain electrons easily

 

17.   Which of the following statements is true regarding typical potassium ions when compared to potassium atoms (K) and argon atoms (Ar)?

 

 

 a.  Potassium ions have a larger radius than either K or Ar atoms.   

 b.  Potassium ions have a larger radius than K atoms, but a smaller radius than Ar atoms.   

 c.  Potassium ions have a smaller radius than either K or Ar atoms.   

 d.  Potassium ions have a smaller radius than K atoms, but a larger radius than Ar atoms.   

 e.  Potassium ions are about the same size as K atoms, but are larger than Ar atoms. 

  

 

 

 

18.   Which of the following statements is true regarding sulphide ions when compared to sulphur atoms (S) and argon atoms (Ar)? 

 

 a.  Sulphide ions have a larger radius than either S or Ar atoms.   

 b.  Sulphide ions have a larger radius than S atoms, but a smaller radius than Ar.   

 c.  Sulphide ions have a smaller radius than either S or Ar atoms.    

 d.  Sulphide ions have a smaller radius than S atoms, but a larger radius than Ar.   

 e.  Sulphide ions have about the same radius as S atoms, but are larger than Ar atoms. 

  

19.   Which of the following tend to have more than one oxidation number: 

   

 a.  alkali metals   

 b.  alkaline earth metals   

 c.  noble gases   

 d.  outer transition metals   

 e.  none of the above; all of the above have only one oxidation number 

 

 

20.   Which of the following is not a typical property of metals? 

   

 a.  good electrical conductivity   

 b.  good conductor of heat   

 c.  malleable (easily shaped)   

 d.  gain electrons easily   

 e.  all of the above are properties of metals 

  

21.   What type of neutral atom has seven electrons in its outer shell? 

 

 a.  alkali metal  

 b.  halogen   

 c.  noble gas 

 d.  rare earth element   

 e.  alkaline earth element 

  

 22.  What type of neutral atom has two electrons in its outer shell? 

   

 a.  alkali metal   

 b.  halogen   

 c.  noble gas   

 d.  alkaline earth element   

 e.  none of the above 

 

23.   What type of neutral atom has eight electrons in its outer shell? 

   

 a.  alkali metal   

 b.  halogen   

 c.  noble gas   

 d.  rare earth element   

 e.  alkaline earth element 

 

  

 

 

24.   What type of neutral atom has one electron in its outer shell? 

 

 a.  alkali metal   

 b.  halogen   

 c.  noble gas   

 d.  rare earth element   

 e.  alkaline earth element 

 

25.   What type of neutral atom has eight electrons in an f subshell? 

   

 a.  alkali metal   

 b.  halogen   

 c.  noble gas   

 d.  rare earth element   

 e.  alkaline earth element 

  

26.   The way in which an atom reacts chemically is determined by: 

   

 a.  the number of neutrons   

 b.  the number of electrons in its outer shell   

 c.  the number of electrons in the lowest energy level 

 d.  the average atomic mass numbers of its isotopes   

 e.  the arrangement of its protons 

 

 

For each of the following, write the symbol for an element that has the electron configuration described:

 

27.   The outer shell of a neutral atom consists of 2 electrons in an s subshell.  The next shell in from the outer shell consists of 2 electrons in an s subshell, 6 electrons in a p subshell, and 8 electrons in a d subshell.  This could be an atom of:  (1 pt.)

 

 

28.   The outer shell of a neutral atom consists of 2 electrons in an s subshell.  The next shell in from the outer shell consists of 2 electrons in an s subshell and 6 electrons in a p subshell.  This could be an atom of:    (1 pt.)

 

  

29.   The outer shell of a neutral atom consists of 2 electrons in an s subshell and 6 electrons in a p subshell.  The next shell in from the outer shell consists of 2 electrons in an s subshell, 6 electrons in a p subshell, and 10 electrons in a d subshell.  This could be an atom of:    (1 pt.)

 

 

Short Answer / Fill in the Blank:  (1 pt. each)

 

30.   How many valence electrons does tellurium (Te) have?  ____

 

31.   How many valence electrons does vanadium (V) have?  ____

 

32.   How many different sublevels are theoretically possible in the sixth energy level?  ____

 

33.   The 5p sublevel may contain up to how many electrons?  ____

 

34.   The number of electrons that can exist in the same orbital of the 4f sublevel is:  ____

 

35.   The number of orbitals theoretically possible in the third energy level is:  ____

 

36.   How many electrons are in the outer energy level of an atom of germanium (Ge)?  ____

 

37.   What element has the following electron configuration?  1s22s22p63s23p5   ______

 

38.   How many electrons are represented by the following electron configuration?  [Ar]4s23d8   ____

 

39.   Write the symbol for an element that has no known compounds.  _____

   

40.   Write the symbol for any rare earth element: _____

 

41.   Write the symbol for any halogen: _____

 

42.   Write the symbol for any alkaline earth element: _____

 

43.   Write the symbol for an element that has three electrons in a d subshell: _____

 

44.   Write the symbol for an element that has one electron in a p subshell: _____

 

45.   Write the symbol for an element that tends to form ions with a +4 charge: ____

 

46.   Write the symbol for an element that has a half-filled s subshell:  _____

 

47.   How many electrons in an atom can have a principal quantum number of 3 and a secondary quantum number of 2?  ____

 

48.   How many electrons in an atom can have a principal quantum number of 4 and a magnetic quantum number of 2?  ____

 

49.   How many electrons in an atom can have a principal quantum number of 2 and a secondary quantum number of 2?  ____

 

50.   How many electrons in an atom can have a principal quantum number of 4 and a spin quantum number of +½ ? ____

 

51.   Write the symbols of the following elements in order of increasing nonmetallic activity (lowest to highest):

  S, Se, Cl, As   (2 pts.)

 

 

52.   Write the symbols of the following elements in order of increasing metallic activity (lowest to highest):

  Fe, Rb, Ca, Cu    (2 pts.)

 

 

 

 

53.   Draw a p orbital.  (1 pt.)

 

 

 

 

 

 

Of the elements K, Ca, Rb, Sr, Se, Br, Te, and I:   (1 pt. each)</